Aqua(2,2′-bipyridine)trifluoridochromium(III) dihydrate
نویسنده
چکیده
The title compound, [CrF(3)(C(10)H(8)N(2))(H(2)O)]·2H(2)O, was prepared by the reaction of CrF(3) and 2,2'-bipyridine under hydrous conditions. The metal centre is coordinated in a distorted octahedral mode by two N atoms from the organic ligand, three F atoms and one O atom of a water molecule. . The crystal packing is stabilized by O-H⋯O and O-H⋯F hydrogen-bonding contacts, which form a one-dimensional belt extending parallel to (100).
منابع مشابه
Tetrakis[μ-3-(3-hydroxyphenyl)propenoato]bis{aqua(2,2′-bipyridine)[3-(3-hydroxyphenyl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate
The dinuclear title compound, [Nd(2)(C(9)H(7)O(3))(6)(C(10)H(8)N(2))(2)]·2C(10)H(8)N(2)·2H(2)O, was synthesized under hydro-thermal conditions. The centrosymmetric complex consists of two nine-coordinated Nd(3+) cations, six 3-hy-droxy-cinnamate anions and two chelating 2,2'-bipyridine mol-ecules. The coordination geometry around the cations can be best described as distorted tricapped trigonal...
متن کاملBis(μ-3-nitrophthalato-κ2 O 1:O 2)bis[aqua(2,2′-bipyridine-κ2 N,N′)copper(II)] dihydrate
Two 3-nitro-phthalate dianions bridge two water-coordinated 2,2'-bipyridine-chelated Cu(II) atoms about a center of inversion to generate the title dinuclear compound, [Cu(2)(C(8)H(3)NO(6))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O. The geometry of the Cu(II) atom is a distorted square pyramid. Adjacent mol-ecules are linked through the coordinated and solvent water mol-ecules to form a linear rib...
متن کاملAqua(2,2′-bipyridine-κ2 N,N′)[2-(3-thienyl)malonato-κ2 O,O′]zinc(II) dihydrate
In the crystal structure of the title compound, [Zn(C(7)H(4)O(4)S)(C(10)H(8)N(2))(H(2)O)]·2H(2)O, the Zn(II) ion assumes a trigonal-bipyramidal coordination geometry completed by two N atoms from a 2,2'-bipyridine ligand, two O atoms from a 2-(3-thien-yl)malonate anion and a water mol-ecule. The S atom of the 2-(3-thien-yl)malonate ligand is disordered over two sites with an occupancy ratio of ...
متن کاملcatena-Poly[[[aqua(2,2′-bipyridine-κ2 N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ2 O 2:O 5] dihydrate]
In the crystal structure of the title compound, {[Cu(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite chain parallel to [110] is formed by the linking of Cu(H(2)O)(2,2'-bipyridine) units through a furan-2,5-dicarboxyl-ate bridge. The Cu(II) atom shows a square-pyramidal geometry, with one furan-2,5-dicarboxyl-ate O atom in the apical position. The dihedral angle between the planes o...
متن کامل[μ-2,2′-(1,4-Phenylene)diacetato-κ2 O 1:O 4]bis[aqua(2,2′-bipyridine-κ2 N,N′)chloridocopper(II)] dihydrate
In the centrosymmetric title compound, [Cu(2)(C(10)H(8)O(4))Cl(2)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, the Cu(II) atom is five-coordinated in a distorted square-pyramidal geometry by two N atoms from a chelating 2,2'-bipyridine ligand, one O atom from a 1,4-phenyl-enediacetate ligand, one Cl atom and one water mol-ecule. The 1,4-phenyl-enediacetate ligand, lying on an inversion center, bridges ...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009